A guest dependent inversion of enantiomeric recognition operated by the host dehydrocholic acid on a second guest is observed during host–guest dehydrocholic acid–sulfoxide assembly formation. We were able to demonstrate the possibility of obtaining the control of the enantiomeric inclusion on (R)- or (S)-methyl phenyl sulfoxide in dehydrocholic acid assemblies via supramolecular chiral recognition induced by a second guest, that is (R)- or (S)-methyl tolyl sulfoxide.
Guest dependent inversion of enantiomeric recognition in dehydrocholic acid host-guest enclathration
BORTOLINI, Olga;FANTIN, Giancarlo;FOGAGNOLO, Marco;PERRONE, Daniela
2007
Abstract
A guest dependent inversion of enantiomeric recognition operated by the host dehydrocholic acid on a second guest is observed during host–guest dehydrocholic acid–sulfoxide assembly formation. We were able to demonstrate the possibility of obtaining the control of the enantiomeric inclusion on (R)- or (S)-methyl phenyl sulfoxide in dehydrocholic acid assemblies via supramolecular chiral recognition induced by a second guest, that is (R)- or (S)-methyl tolyl sulfoxide.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
