A guest dependent inversion of enantiomeric recognition operated by the host dehydrocholic acid on a second guest is observed during host–guest dehydrocholic acid–sulfoxide assembly formation. We were able to demonstrate the possibility of obtaining the control of the enantiomeric inclusion on (R)- or (S)-methyl phenyl sulfoxide in dehydrocholic acid assemblies via supramolecular chiral recognition induced by a second guest, that is (R)- or (S)-methyl tolyl sulfoxide.

Guest dependent inversion of enantiomeric recognition in dehydrocholic acid host-guest enclathration

BORTOLINI, Olga;FANTIN, Giancarlo;FOGAGNOLO, Marco;PERRONE, Daniela
2007

Abstract

A guest dependent inversion of enantiomeric recognition operated by the host dehydrocholic acid on a second guest is observed during host–guest dehydrocholic acid–sulfoxide assembly formation. We were able to demonstrate the possibility of obtaining the control of the enantiomeric inclusion on (R)- or (S)-methyl phenyl sulfoxide in dehydrocholic acid assemblies via supramolecular chiral recognition induced by a second guest, that is (R)- or (S)-methyl tolyl sulfoxide.
2007
Bortolini, Olga; Fantin, Giancarlo; Fogagnolo, Marco; Perrone, Daniela
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/517951
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