Addition of both Grignard reagents or hydride reducing agents to the ester group of the readily available 2,4-dioxoalkanoates, while the 1,3-diketone fragment is suitably masked both in form of an isoxazole ring or as an enaminone function, allows a useful preparation of a variety of α'-hydroxy-1, 3-diketone moieties. Acid-promoted cyclodehydration of these compounds leads to 3(2H) furanones or 3(2H) furanimines depending on the substitution pattern and on reaction conditions.
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Data di pubblicazione: | 1987 | |
Titolo: | Ethyl 2,4-dioxoalkanoates as starting materials for a convenient route to 3(2H)-furanones and 3(2H)-furanimines. | |
Autori: | P. BARALDI; BARCO ACHILLE; BENETTI SIMONETTA; MANFREDINI STEFANO; POLLINI GIAN PIERO; SIMONI DANIELE. | |
Rivista: | TETRAHEDRON | |
Abstract: | Addition of both Grignard reagents or hydride reducing agents to the ester group of the readily available 2,4-dioxoalkanoates, while the 1,3-diketone fragment is suitably masked both in form of an isoxazole ring or as an enaminone function, allows a useful preparation of a variety of α'-hydroxy-1, 3-diketone moieties. Acid-promoted cyclodehydration of these compounds leads to 3(2H) furanones or 3(2H) furanimines depending on the substitution pattern and on reaction conditions. | |
Handle: | http://hdl.handle.net/11392/460426 | |
Appare nelle tipologie: | 03.1 Articolo su rivista |
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