Pyrimidine, pyrazole, imidazole and purine N-tetrahydropyranyl (THP) derivatives have been converted in one-pot and in a regio- and stereo-selective manner into the corresponding β-D-2′,3′,5′-tri-O-benzoyl ribofuranosyl nucleoside derivatives on treatment with 1-β-acetyl-2′,3′,5′-tri-O-benzoyl-ribofuranose, hexamethyldisilazane (HMDS), trimethylsilyl chloride (TMSCI), and trimethylsilyl triflate (TMST).

A new direct glycosylation of pyrimidine, pyrazole, imidazole and purine heterocycles via their N-tetrahydropyranyl (THP) derivatives

MANFREDINI, Stefano;BARALDI, Pier Giovanni;SIMONI, Daniele
1994

Abstract

Pyrimidine, pyrazole, imidazole and purine N-tetrahydropyranyl (THP) derivatives have been converted in one-pot and in a regio- and stereo-selective manner into the corresponding β-D-2′,3′,5′-tri-O-benzoyl ribofuranosyl nucleoside derivatives on treatment with 1-β-acetyl-2′,3′,5′-tri-O-benzoyl-ribofuranose, hexamethyldisilazane (HMDS), trimethylsilyl chloride (TMSCI), and trimethylsilyl triflate (TMST).
Manfredini, Stefano; Baraldi, Pier Giovanni; Bazzanini, Rita; Guarneri, Mario; Simoni, Daniele
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/460356
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