A series of composite CdS/TiO2 powders was obtained by nucleation of TiO2 on CdS nanoseeds. This combination presents the appropriate band edge position for photocatalytic redox reactions: visible light irradiation of CdS allows the injection of electrons into dark TiO2, increasing the lifetimes of separated charges. The electrons have been used for the quantitative photoreduction of 4-nitrobenzaldehyde to 4-aminobenzaldehyde, whose formation was pointed out by 1H NMR and ESI-MS positive ion mode. Concomitant sacrificial oxidation of 2-propanol, which was also the proton source, occurred. The use of characterization techniques (XRD, N2 adsorption-desorption) evidenced the principal factors driving the photocatalytic reaction: the nanometric size of anatase crystalline domains, the presence of dispersed CdS to form an extended active junction CdS/anatase, and the presence of mesopores as nanoreactors. The result is an efficient photocatalytic system that uses visible light. In addition, the presence of TiO2 in combination with CdS improves the stability of the photoactive material, enabling its recyclability.
A series of composite CdS/TiO2 powders was obtained by nucleation of TiO2 on CdS nanoseeds. This combination presents the appropriate band edge position for photocatalytic redox reactions: visible light irradiation of CdS allows the injection of electrons into dark TiO2, increasing the lifetimes of separated charges. The electrons have been used for the quantitative photoreduction of 4-nitrobenzaldehyde to 4-aminobenzaldehyde, whose formation was pointed out by 1H NMR and ESI-MS positive ion mode. Concomitant sacrificial oxidation of 2-propanol, which was also the proton source, occurred. The use of characterization techniques (XRD, N2 adsorption-desorption) evidenced the principal factors driving the photocatalytic reaction: the nanometric size of anatase crystalline domains, the presence of dispersed CdS to form an extended active junction CdS/anatase, and the presence of mesopores as nanoreactors. The result is an efficient photocatalytic system that uses visible light. In addition, the presence of TiO2 in combination with CdS improves the stability of the photoactive material, enabling its recyclability.
Composite CdS/TiO2 Powders for the Selective Reduction of 4-Nitrobenzaldehyde by Visible Light: Relation between Preparation, Morphology and Photocatalytic Activity
Martina Milani;Michele Mazzanti;Stefano Caramori;Graziano Di Carmine;Alessandra Molinari
2023
Abstract
A series of composite CdS/TiO2 powders was obtained by nucleation of TiO2 on CdS nanoseeds. This combination presents the appropriate band edge position for photocatalytic redox reactions: visible light irradiation of CdS allows the injection of electrons into dark TiO2, increasing the lifetimes of separated charges. The electrons have been used for the quantitative photoreduction of 4-nitrobenzaldehyde to 4-aminobenzaldehyde, whose formation was pointed out by 1H NMR and ESI-MS positive ion mode. Concomitant sacrificial oxidation of 2-propanol, which was also the proton source, occurred. The use of characterization techniques (XRD, N2 adsorption-desorption) evidenced the principal factors driving the photocatalytic reaction: the nanometric size of anatase crystalline domains, the presence of dispersed CdS to form an extended active junction CdS/anatase, and the presence of mesopores as nanoreactors. The result is an efficient photocatalytic system that uses visible light. In addition, the presence of TiO2 in combination with CdS improves the stability of the photoactive material, enabling its recyclability.I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
