The novel conjugate 1, featuring two l-tyrosinato residues axially coordinated to the tin centre of a Sn(iv)-tetraphenylporphyrin, is reported as the first example of a supramolecular dyad for photochemical PCET. It is noteworthy that the excitation of 1 in the presence of a suitable base is followed by photoinduced PCET leading to a radical pair state with a surprisingly long lifetime.
Formation of a long-lived radical pair in a Sn(iv) porphyrin-di(l-tyrosinato) conjugate driven by proton-coupled electron-transfer
Mirco Natali
Primo
;
2018
Abstract
The novel conjugate 1, featuring two l-tyrosinato residues axially coordinated to the tin centre of a Sn(iv)-tetraphenylporphyrin, is reported as the first example of a supramolecular dyad for photochemical PCET. It is noteworthy that the excitation of 1 in the presence of a suitable base is followed by photoinduced PCET leading to a radical pair state with a surprisingly long lifetime.File in questo prodotto:
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