Racemic secondary esters, lactones, and styrene oxide are kinetically resolved via hydrolysis with Yarrowia Lipolytica YL2 strains. The enantioselective hydrolysis of prochiral enol esters to the corresponding homochiral carbonyl compounds is also described. Subsequent reduction of the ketone and of the aldehyde can be avoided usin lyophilised cells.
Enantioselective hydrolyses with Yarrowia lipolytica: a versatile strain for esters, enol esters, epoxides, and lactones
FANTIN, GiancarloPrimo
;FOGAGNOLO, MarcoSecondo
;GUERRINI, Alessandra;MEDICI, Alessandro
;PEDRINI, PaolaPenultimo
;
2001
Abstract
Racemic secondary esters, lactones, and styrene oxide are kinetically resolved via hydrolysis with Yarrowia Lipolytica YL2 strains. The enantioselective hydrolysis of prochiral enol esters to the corresponding homochiral carbonyl compounds is also described. Subsequent reduction of the ketone and of the aldehyde can be avoided usin lyophilised cells.File in questo prodotto:
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