The asymmetric epoxidation of unfunctionalized olefins has been achieved using 3-keto bile acids as optically active inducers and Oxone. Opposite enantioselectivities may be obtained depending on the specific substitution of the bile acids.
Control of the Enantioselectivity by Keto Bile Acid Derivatives in the Epoxidation of Alkenes with Oxone.
BORTOLINI, Olga;FANTIN, Giancarlo;FOGAGNOLO, Marco;MARI, Lara
2004
Abstract
The asymmetric epoxidation of unfunctionalized olefins has been achieved using 3-keto bile acids as optically active inducers and Oxone. Opposite enantioselectivities may be obtained depending on the specific substitution of the bile acids.File in questo prodotto:
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