The synthesis, spectroscopic and chromatographic characterization, and X-ray crystal structure of the complex tris(2-methoxyisobutylisocyano) copper(I) tetrafluoroborate, [Cu(MIBI)(3)][BF4], is reported. The Cu atom lies on threefold axis and is bonded to three 2-methoxyisobutylisocyano ligands in a perfect trigonal-planar coordination. The calculated and experimental powder-diffraction spectra of this complex are also reported.

Synthesis, characterizition ad X-ray crystal structure of the trigonal-planar copper (1) complex [Cu(MIBI)(3)](+) (MIBI=2-methoxyisobutylisocyanide)

PASQUALI, Micol;FERRETTI, Valeria;DUATTI, Adriano
2008

Abstract

The synthesis, spectroscopic and chromatographic characterization, and X-ray crystal structure of the complex tris(2-methoxyisobutylisocyano) copper(I) tetrafluoroborate, [Cu(MIBI)(3)][BF4], is reported. The Cu atom lies on threefold axis and is bonded to three 2-methoxyisobutylisocyano ligands in a perfect trigonal-planar coordination. The calculated and experimental powder-diffraction spectra of this complex are also reported.
2008
Pasquali, Micol; Ferretti, Valeria; Duatti, Adriano
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/533233
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