The base-catalysed ring closure of 2,6-dinitrophenylsulfanylethanenitrile and 2,4,6-trinitrophenylsulfanylethanenitrile gives 2-cyano-7- nitrobenzo[d]thiazole-3-oxide and 2-cyano-5,7-dinitrobenzo[d]thiazole-3-oxide, respectively. Structure of the starting phenylsulfanyl-ethanenitriles has been studied both in crystal and in solution.
STRUCTURE OF 2,6-DINITROPHENYLSULFANYLETHANENITRILE AND 2,4,6-TRINITROPHENYLSULFANYLETHANENITRILE AND THEIR RING CLOSURE GIVING 2-CYANOBENZO[d]THIAZOLE-3- OXIDES
BERTOLASI, Valerio;
2008
Abstract
The base-catalysed ring closure of 2,6-dinitrophenylsulfanylethanenitrile and 2,4,6-trinitrophenylsulfanylethanenitrile gives 2-cyano-7- nitrobenzo[d]thiazole-3-oxide and 2-cyano-5,7-dinitrobenzo[d]thiazole-3-oxide, respectively. Structure of the starting phenylsulfanyl-ethanenitriles has been studied both in crystal and in solution.File in questo prodotto:
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