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EnglishIn real catalyst system, it si difficult to establish a correlation between catalytic properties and the shape (crystal planes, corners and steps) of the active catalytic particles. In this paper we present a clear shape dependence of the catalytic properties of a Vulcan-supported fuel cell catalyst having 4 nm cubo-octahedral platinum(0) nanocrystallites with (111) and (100) surfaces stabilized by sodium polyacrylate. The electrode materials were characterized by CO-stripping cyclic voltammetry and transmission electron microscopy (TEM), showing that no agglomeration had occured among the nanoparticles on the catalyst surfaces.
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| Data di pubblicazione: | 2008 | |
| Titolo: | Dependence of CO oxidation on Pt nanoparticle shape: a shape-selective approach to the synthesis of PEMFC catalysts | |
| Autori: | S. Kinge; Ch. Urgeghe; A. De Battisti; H. Boennemann | |
| Rivista: | APPLIED ORGANOMETALLIC CHEMISTRY | |
| Abstract: | In real catalyst system, it si difficult to establish a correlation between catalytic properties and the shape (crystal planes, corners and steps) of the active catalytic particles. In this paper we present a clear shape dependence of the catalytic properties of a Vulcan-supported fuel cell catalyst having 4 nm cubo-octahedral platinum(0) nanocrystallites with (111) and (100) surfaces stabilized by sodium polyacrylate. The electrode materials were characterized by CO-stripping cyclic voltammetry and transmission electron microscopy (TEM), showing that no agglomeration had occured among the nanoparticles on the catalyst surfaces. | |
| Digital Object Identifier (DOI): | 10.1002/aoc.1349 | |
| Handle: | http://hdl.handle.net/11392/523494 | |
| Appare nelle tipologie: | 03.1 Articolo su rivista |
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