A cyclopropyl ring-opening/nitrilium ion ring-closing tandem reaction has been conveniently used in an expeditious synthetic approach to light-driven Z /E molecular switches featuring an imine function conjugated to olefin groups that mimics natural protonated Schiff bases.
Synthesis of bio-mimetic light-driven molecular switches via a cyclopropyl ring-opening/nitrilium ion ring-closing tandem reaction
ZANIRATO, Vinicio;POLLINI, Gian Piero;DE RISI, Carmela;VALENTE, Filippo;
2007
Abstract
A cyclopropyl ring-opening/nitrilium ion ring-closing tandem reaction has been conveniently used in an expeditious synthetic approach to light-driven Z /E molecular switches featuring an imine function conjugated to olefin groups that mimics natural protonated Schiff bases.File in questo prodotto:
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