We have shown that nonnatural protonated Schiff bases constitute prototypes for the development of a novel class of light-driven biomimetic switches featuring a rigid molecular framework and a fully selective Z/E photoisomerization. Most importantly, these molecules promise to expand the use of Z/E switches well beyond the applications of the Ab switch.
Quantum Chemical Modeling and Preparation of a Biomimetic Photochemical Switch
ZANIRATO, Vinicio;
2007
Abstract
We have shown that nonnatural protonated Schiff bases constitute prototypes for the development of a novel class of light-driven biomimetic switches featuring a rigid molecular framework and a fully selective Z/E photoisomerization. Most importantly, these molecules promise to expand the use of Z/E switches well beyond the applications of the Ab switch.File in questo prodotto:
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