The nitroarene p-nitrotoluene is converted with a selectivity higher than 85% to the corresponding carbamate at room temperature and atmospheric pressure, using photoexcited particles of TiO2 as catalyst and EtOH as carbonylating species.
PHOTOCATALYTIC FORMATION OF A CARBAMATE THROUGH ETHANOL-ASSISTED CARBONYLATION OF P-NITROTOLUENE
MALDOTTI, Andrea;SAMIOLO, Luca;MOLINARI, Alessandra;
2005
Abstract
The nitroarene p-nitrotoluene is converted with a selectivity higher than 85% to the corresponding carbamate at room temperature and atmospheric pressure, using photoexcited particles of TiO2 as catalyst and EtOH as carbonylating species.File in questo prodotto:
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