N,N dimethyltetradecylamine N-oxide (DTAO) is an appropriate surfactant to form micelles able to host the iron (III) meso-tetrakis(2,6dichlorophenyl)porphrin. The so obtained microheterogeneous catalyst can induce biomimetic redox processes on organic substrates in aqueous medium, using sunlight and oxygen as clean reagents.
PHOTOCATALYTIC PROPERTIES OF IRON PORPHYRINS REVISITED IN AQUEOUS MICELLAR ENVIRONMENT: OXYGENATION OF ALKENES AND REDUCTIVE DEGRADATION OF CARBON TETRACHLORIDE
MALDOTTI, Andrea;MOLINARI, Alessandra;VARANI, Graziano;
2001
Abstract
N,N dimethyltetradecylamine N-oxide (DTAO) is an appropriate surfactant to form micelles able to host the iron (III) meso-tetrakis(2,6dichlorophenyl)porphrin. The so obtained microheterogeneous catalyst can induce biomimetic redox processes on organic substrates in aqueous medium, using sunlight and oxygen as clean reagents.File in questo prodotto:
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