Heterogenization of iron porphyrins inside Nafion creates new photocatalytic systems which can be used to oxidize cyclohexene and cyclohexane with sunlight and O2 under mild conditions (room temperature, atmospheric pressure); the polymeric matrix makes the iron porphyrin a good photocalyst for the monooxygenation of the substrate and increases both its photocatalytic efficiency (about ten times) and its stability (turnover values > 1000).

NOVEL REACTIVITY OF PHOTOEXCITED IRON PORPHYRINS CAGED INTO A POLYFLUOROSULFONATED MEMBRANE IN CATALYTIC HYDROCARBON OXYGENATION

MALDOTTI, Andrea;MOLINARI, Alessandra;FOGAGNOLO, Marco;AMADELLI, Rossano
1998

Abstract

Heterogenization of iron porphyrins inside Nafion creates new photocatalytic systems which can be used to oxidize cyclohexene and cyclohexane with sunlight and O2 under mild conditions (room temperature, atmospheric pressure); the polymeric matrix makes the iron porphyrin a good photocalyst for the monooxygenation of the substrate and increases both its photocatalytic efficiency (about ten times) and its stability (turnover values > 1000).
1998
Maldotti, Andrea; Molinari, Alessandra; L., Andreotti; Fogagnolo, Marco; Amadelli, Rossano
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/471068
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