The installation of the 2-furyl ring at the anomeric carbon of 2,3,4,6-tetra-O-benzyl-D-glucopyranose and 2,3:5,6-di-O-isopropylidene-D-mannofuranose is carried out either by addition of 2-lithiofuran to the correspondinglactones either by direct C-glycosidation of the O-acetyl derivatives with furan; the resultant 2-furyl C-glycosides are converted to carboxylic acids by the oxidative cleavage of the furan nucleous. © 1993.

FURAN-BASED SYNTHESIS OF C-GLYCOSYL CARBOXYLATES

DONDONI, Alessandro;MARRA, Alberto;
1993

Abstract

The installation of the 2-furyl ring at the anomeric carbon of 2,3,4,6-tetra-O-benzyl-D-glucopyranose and 2,3:5,6-di-O-isopropylidene-D-mannofuranose is carried out either by addition of 2-lithiofuran to the correspondinglactones either by direct C-glycosidation of the O-acetyl derivatives with furan; the resultant 2-furyl C-glycosides are converted to carboxylic acids by the oxidative cleavage of the furan nucleous. © 1993.
1993
Dondoni, Alessandro; Marra, Alberto; Scherrmann, Mc
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/462241
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