The reactions of trans-ReOCl3(PPh3)2 with vinyl amides such as RCOCH=C(R′)NH2, where R′ = CH2CH2CO2H and R = Ph and C6H13; or R′ = Me, CH2CH2CO2Me and R = Ph, give complexes of the type ReOCl2-[RC(O-)=CHC(R′)=NH]PPh3, the coordination geometry of which have been deduced from i.r. and1H n.m.r. spectroscopic data. © 1981 Verlag Chemie GmbH.
RHENIUM(V) COMPLEXES WITH VINYL AMIDES
DUATTI, Adriano;
1981
Abstract
The reactions of trans-ReOCl3(PPh3)2 with vinyl amides such as RCOCH=C(R′)NH2, where R′ = CH2CH2CO2H and R = Ph and C6H13; or R′ = Me, CH2CH2CO2Me and R = Ph, give complexes of the type ReOCl2-[RC(O-)=CHC(R′)=NH]PPh3, the coordination geometry of which have been deduced from i.r. and1H n.m.r. spectroscopic data. © 1981 Verlag Chemie GmbH.File in questo prodotto:
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