The complex [Tc(PPh3)2(CO)3Cl] reacts with the lithium salt of amido-carboxylato- and thiazolato-derivatives to give the new complexes[Figure not available: see fulltext.] (Ar= C6H4Me-p or C6H4OMe-p), [Tc(PPh3)2(CO)2(amt1,2)] [amt1=anion of 2-(methylamino)thiazole; amt2=anion of 2-4-methoxyphenylamino(thiazole)] and [Tc(PPh3)2(CO)2-[Figure not available: see fulltext.] (R = Ph2CH, PhCH2 or CCl3). The compounds have been characterized by elemental analysis, and i.r. and1H n.m.r. spectra. © 1986 VCH Verlagsgesellschaft mbH.
PREPARATION AND CHARACTERIZATION OF MIXED AMIDO, CARBOXYLATO OR THIAZOLATO CARBONYL(PHOSPHINE)TECHNETIUM(I) COMPLEXES
DUATTI, Adriano;
1986
Abstract
The complex [Tc(PPh3)2(CO)3Cl] reacts with the lithium salt of amido-carboxylato- and thiazolato-derivatives to give the new complexes[Figure not available: see fulltext.] (Ar= C6H4Me-p or C6H4OMe-p), [Tc(PPh3)2(CO)2(amt1,2)] [amt1=anion of 2-(methylamino)thiazole; amt2=anion of 2-4-methoxyphenylamino(thiazole)] and [Tc(PPh3)2(CO)2-[Figure not available: see fulltext.] (R = Ph2CH, PhCH2 or CCl3). The compounds have been characterized by elemental analysis, and i.r. and1H n.m.r. spectra. © 1986 VCH Verlagsgesellschaft mbH.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.