Mixed cation perovskites, [HC(NH2)2]xCs(1−x)PbI3, (FAxCs(1−x)PbI3) with x = 0.8 achieve high solar cell power conversion efficiencies (PCEs) while exhibiting long-term stability under ambient conditions. In this work, we perform density functional theory (DFT) calculations, first-principles molecular dynamics (MD) simulations, solid-state nuclear magnetic resonance (NMR) and X-ray powder diffraction (XRD) measurements aimed at investigating the possible phase stability of Cs+-rich FAxCs(1−x)PbI3, mixed-cation materials as potential candidate for tandem solar cell applications.
Atomistic origins of the limited phase stability of Cs+-rich FAxCs(1-x)PbI3 mixtures
Meloni, Simone;
2020
Abstract
Mixed cation perovskites, [HC(NH2)2]xCs(1−x)PbI3, (FAxCs(1−x)PbI3) with x = 0.8 achieve high solar cell power conversion efficiencies (PCEs) while exhibiting long-term stability under ambient conditions. In this work, we perform density functional theory (DFT) calculations, first-principles molecular dynamics (MD) simulations, solid-state nuclear magnetic resonance (NMR) and X-ray powder diffraction (XRD) measurements aimed at investigating the possible phase stability of Cs+-rich FAxCs(1−x)PbI3, mixed-cation materials as potential candidate for tandem solar cell applications.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
10.1021@acs.chemmater.0c00120.pdf
accesso aperto
Tipologia:
Post-print
Licenza:
Creative commons
Dimensione
2.55 MB
Formato
Adobe PDF
|
2.55 MB | Adobe PDF | Visualizza/Apri |
|
boziki2020.pdf
solo gestori archivio
Tipologia:
Full text (versione editoriale)
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
3.12 MB
Formato
Adobe PDF
|
3.12 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
