Careful product analysis in combination with appropriate supporting experiments unambiguously proves that in contrast to what was previously reported, generation of the phosphonium salt from a β-cyclocitral-derived allylic alcohol and PPh3HBr takes place via a protondriven elimination/addition path.
Sometimes, the Least Demanding Solution Is the Most Suitable: A Careful Survey of NMR Spectra of a Phosphonium Salt Accounted for Its “Unusual Wittig Reaction”
Anna FantinatiPrimo
Membro del Collaboration Group
;Paolo MArchettiSecondo
Membro del Collaboration Group
;Claudio Trapella
Penultimo
Membro del Collaboration Group
;Vinicio ZaniratoUltimo
Membro del Collaboration Group
2018
Abstract
Careful product analysis in combination with appropriate supporting experiments unambiguously proves that in contrast to what was previously reported, generation of the phosphonium salt from a β-cyclocitral-derived allylic alcohol and PPh3HBr takes place via a protondriven elimination/addition path.File in questo prodotto:
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ACS OMEGA TRAP 2018.pdf
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