Careful product analysis in combination with appropriate supporting experiments unambiguously proves that in contrast to what was previously reported, generation of the phosphonium salt from a β-cyclocitral-derived allylic alcohol and PPh3HBr takes place via a protondriven elimination/addition path.

Sometimes, the Least Demanding Solution Is the Most Suitable: A Careful Survey of NMR Spectra of a Phosphonium Salt Accounted for Its “Unusual Wittig Reaction”

Anna Fantinati
Primo
Membro del Collaboration Group
;
Paolo MArchetti
Secondo
Membro del Collaboration Group
;
Claudio Trapella
Penultimo
Membro del Collaboration Group
;
Vinicio Zanirato
Ultimo
Membro del Collaboration Group
2018

Abstract

Careful product analysis in combination with appropriate supporting experiments unambiguously proves that in contrast to what was previously reported, generation of the phosphonium salt from a β-cyclocitral-derived allylic alcohol and PPh3HBr takes place via a protondriven elimination/addition path.
2018
Fantinati, Anna; Marchetti, Paolo; Trapella, Claudio; Zanirato, Vinicio
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2399262
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