Here we report the synthesis at low temperature (220 °C) by a solvothermal method of highly crystalline LiCoPO4. This material is a candidate for application as cathode in next-generation Li-ion cells. The presented synthetic route allows a careful tailoring of the sample morphology and leads to morphologically homogeneous platelet-like particles. The obtained material has been characterized by synchrotron radiation X-ray diffraction, vibrational spectroscopies, X-ray photoemission spectroscopy and electron microscopies. The synthesized material has been also characterized in lithium cells to highlight its ability to reversibly cycle lithium.

Controlled synthesis of LiCoPO4by a solvo-thermal method at 220 °c

Di Lecce, D.;
2015

Abstract

Here we report the synthesis at low temperature (220 °C) by a solvothermal method of highly crystalline LiCoPO4. This material is a candidate for application as cathode in next-generation Li-ion cells. The presented synthetic route allows a careful tailoring of the sample morphology and leads to morphologically homogeneous platelet-like particles. The obtained material has been characterized by synchrotron radiation X-ray diffraction, vibrational spectroscopies, X-ray photoemission spectroscopy and electron microscopies. The synthesized material has been also characterized in lithium cells to highlight its ability to reversibly cycle lithium.
Brutti, S.; Manzi, J.; De Bonis, A.; Di Lecce, D.; Vitucci, F.; Paolone, A.; Trequattrini, F.; Panero, S.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2385941
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