A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.

Zinc Porphyrin−Re(I) Bipyridyl−Fullerene Triad: Synthesis, Characterization, and Kinetics of the Stepwise Electron-Transfer Processes Initiated by Visible Excitation

INDELLI, Maria Teresa;
2015

Abstract

A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.
2015
Cavigli, P; Da Ros, T; Kahnt, A; Gamberoni, M; Indelli, Maria Teresa; Lengo, E.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2338887
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