The communication reports the synthesis, characterization, and magnetic behavior of a novel µ4-carbonato supported and imidazole capped ligated nickel cage [Ni8(µ-H2bpmp)4(µ4-CO3)4(ImH)8]-(NO3)4·2H2O (1) through self-assembly of ligand bound ferromagnetic Ni2 building blocks. Structural analysis indicates newer geometrical features for the coordination cage formation and dominant interdimer antiferromagnetic coupling resulting in a diamagnetic ground state.
Self-assembly of a [Ni8] carbonate cube incorporating four µ4-carbonato linkers through fixation of atmospheric CO2 by ligated [Ni2] complexes
BERTOLASI, Valerio;
2014
Abstract
The communication reports the synthesis, characterization, and magnetic behavior of a novel µ4-carbonato supported and imidazole capped ligated nickel cage [Ni8(µ-H2bpmp)4(µ4-CO3)4(ImH)8]-(NO3)4·2H2O (1) through self-assembly of ligand bound ferromagnetic Ni2 building blocks. Structural analysis indicates newer geometrical features for the coordination cage formation and dominant interdimer antiferromagnetic coupling resulting in a diamagnetic ground state.File in questo prodotto:
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