Kinetic theories of liquid chromatography play a key role in evaluating the performance of stationary phases. The conventionally used plate-height equations and the band broadening occurring in different areas of liquid chromatography are accounted for by kinetic models. In this chapter, the most important macroscopic (lumped-kinetic, lumped-pore, and general-rate) and microscopic (stochastic-dispersive) models are discussed. The plate-height equations arising from those kinetic models are discussed and compared.
Kinetic Theories of Liquid Chromatography
CAVAZZINI, Alberto
2013
Abstract
Kinetic theories of liquid chromatography play a key role in evaluating the performance of stationary phases. The conventionally used plate-height equations and the band broadening occurring in different areas of liquid chromatography are accounted for by kinetic models. In this chapter, the most important macroscopic (lumped-kinetic, lumped-pore, and general-rate) and microscopic (stochastic-dispersive) models are discussed. The plate-height equations arising from those kinetic models are discussed and compared.File in questo prodotto:
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