The phosphorescence lifetimes of the (nπ*)3 excited states of HCHO, CH3CHO and (CH3)2CO have been calculated by an ab initio configuration interaction method. The results indicate that the preferentially generated reaction products obtainable from the thermal dissociation of 1,2-dioxetanes have only small differences in the phosphorescence lifetime.
A theoretical study of the phosphorescence lifetimes of H_2CO, CH_3CHO and (CH_3)_2CO
CIMIRAGLIA, Renzo
1982
Abstract
The phosphorescence lifetimes of the (nπ*)3 excited states of HCHO, CH3CHO and (CH3)2CO have been calculated by an ab initio configuration interaction method. The results indicate that the preferentially generated reaction products obtainable from the thermal dissociation of 1,2-dioxetanes have only small differences in the phosphorescence lifetime.File in questo prodotto:
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