The lithium enolate of a butanediacetal-protected glycerate derivative undergoes efficient and diastereoselective alkylation to afford a new fully substituted stereogenic center. These compounds may be elaborated to stable 2-substituted glyceraldehyde derivatives.
A Convenient Route to Enantiomerically Pure 2-Substituted Methyl Glycerate Derivatives
TRAPELLA, Claudio;
2003
Abstract
The lithium enolate of a butanediacetal-protected glycerate derivative undergoes efficient and diastereoselective alkylation to afford a new fully substituted stereogenic center. These compounds may be elaborated to stable 2-substituted glyceraldehyde derivatives.File in questo prodotto:
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