An intramolecular electron transfer can occur in iron porphyrins when irradiated with light of wavelengths corresponding to axial ligand to metal charge transfer transitions. The products of the primary photoprocess can efficiently induce catalytic reactions which follow a biomimetic mechanism.
Biomimetic photocatalysis: iron porphyrins in oxygen activation processes
MALDOTTI, Andrea;BARTOCCI, Carlo;AMADELLI, Rossano;VARANI, Graziano;MOLINARI, Alessandra;
1995
Abstract
An intramolecular electron transfer can occur in iron porphyrins when irradiated with light of wavelengths corresponding to axial ligand to metal charge transfer transitions. The products of the primary photoprocess can efficiently induce catalytic reactions which follow a biomimetic mechanism.File in questo prodotto:
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