Binding of fluorine containing anions by new cationic Co(III) complex: Competitive interaction of chloride and hexafluorophosphate with [Co(phen)(H(2)biim)(2)](3+)

A new mixed ligand cobalt(III) complex salt [Co(phen)(H2biim) 2]Cl3 (1) (where phen = 1,10-phenanthroline, H 2biim = 2,2′-biimidazole) has been synthesized for the first time. In an effort to explore this new cationic complex [Co(phen)(H 2biim)2]3+ as binding agent for fluoroanions, complex salt [Co(phen)(H2biim)2](PF6) 2Cl·2H2O(2) has been synthesized and characterized. Single crystal X-ray structure determination has revealed that complex salt 2 crystallizes in monoclinic crystal system with space group P21/c and consist of one complex cation, one chloride, two hexafluorophosphate anions and two water molecules of crystallization. The packing analyses revealed that the complex cations are arranged in such a way that N-H groups of biimidazole moiety are involved in N-H⋯Cl interaction with chloride ion while C-H groups of phen/H2biim are involved in C-H⋯F interaction with hexafluorophosphate to keep these groups in close proximity. A strong network of hydrogen bond interactions C-H⋯F, N-H⋯O, N-H⋯Cl, C-H⋯O (water) and O-H⋯O (water) are responsible for the stabilization of 3D supramolecular architecture. To the best of our knowledge, this is the first crystal structure of any salt containing the cation [Co(phen)(H2biim)2]3+. © 2011 Elsevier B.V. All rights reserved.