1,5,7-Triazabicyclo[4.4.0]dec-1- ene (TBD), 7-Methyl-TBD (MTBD) and the polymer-supported TBD (P-TBD):Three efficient  catalysts for the nitroaldol (Henry) reaction and for the addition of dialkyl phosphites to unsaturated  systems.

Simoni, D.; Rondanin, R.; Morini, M.; Baruchello, R.; Invidiata, F. P.

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The 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and its 7-methyl derivative (MTBD) have been proven to be of great synthetic utility as catalysts in the nitroaldol (Henry) reaction and for the addition of dialkyl phosphites to a variety of carbonyl compounds. The catalysts were in many cases superior to the parent tetramethylguanidine (TMG). In general the reaction proceeds in a few minutes at 0°C. The polymer-supported-TBD (P-TBD) was also proven to be an efficient promoter of the above cited nucleophilic additions.

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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11392/1208177

Titolo:	1,5,7-Triazabicyclo[4.4.0]dec-1- ene (TBD), 7-Methyl-TBD (MTBD) and the polymer-supported TBD (P-TBD):Three efficient catalysts for the nitroaldol (Henry) reaction and for the addition of dialkyl phosphites to unsaturated systems.
Autori interni:	SIMONI, Daniele RONDANIN, Riccardo BARUCHELLO, Riccardo
Data di pubblicazione:	2000
Rivista:	TETRAHEDRON LETTERS
Abstract:	The 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and its 7-methyl derivative (MTBD) have been proven to be of great synthetic utility as catalysts in the nitroaldol (Henry) reaction and for the addition of dialkyl phosphites to a variety of carbonyl compounds. The catalysts were in many cases superior to the parent tetramethylguanidine (TMG). In general the reaction proceeds in a few minutes at 0°C. The polymer-supported-TBD (P-TBD) was also proven to be an efficient promoter of the above cited nucleophilic additions.
Handle:	http://hdl.handle.net/11392/1208177
Appare nelle tipologie:	03.1 Articolo su rivista

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