Preparation of various optically active heteroaryl propanols for microbial redox is described. The kinetic resolution of the racemic propanols is obtained via oxidation with Bacillus stearothermophilus ( R-alcohols, ee 74-100%). The reduction of propanones with baker’s yeast gives the S-alcohols (ee 100%).
Homochiral (R)- and (S)-1-Heteroaryl- and 1-Aryl-2-propanols via Microbial Redox
FOGAGNOLO, Marco
Primo
;GIOVANNINI, Pier PaoloSecondo
;GUERRINI, Alessandra;MEDICI, Alessandro;PEDRINI, PaolaPenultimo
;
1998
Abstract
Preparation of various optically active heteroaryl propanols for microbial redox is described. The kinetic resolution of the racemic propanols is obtained via oxidation with Bacillus stearothermophilus ( R-alcohols, ee 74-100%). The reduction of propanones with baker’s yeast gives the S-alcohols (ee 100%).File in questo prodotto:
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