[3+2] Nitrile oxide cycloaddition chemistry has been conveniently applied as carbon-carbon bond forming reaction for the assemblage of the functionalized carbon atom fragments required for the synthesis of two simple but different targets such as (-)-pyrenophorin and rosefuran. In both cases, an intermediate 3,5-disubstituted isoxazoline ring system has been used as serviceable precursor of the salient structural feature of the targets.
A [3+2]nitrile oxide cycloaddition approach to (-)-pyrenophorin, and rosefuran
BARCO, Achille;BENETTI, Simonetta;DE RISI, Carmela;POLLINI, Gian Piero;ZANIRATO, Vinicio
1995
Abstract
[3+2] Nitrile oxide cycloaddition chemistry has been conveniently applied as carbon-carbon bond forming reaction for the assemblage of the functionalized carbon atom fragments required for the synthesis of two simple but different targets such as (-)-pyrenophorin and rosefuran. In both cases, an intermediate 3,5-disubstituted isoxazoline ring system has been used as serviceable precursor of the salient structural feature of the targets.File in questo prodotto:
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