The Edgeworth-Cramér series peak handling method has been used to detect the onset of small variations of chromatographic peak shape when the mass of solute injected is increased. The eflect of extracolumn distortion on statistical peak parameters and on the resultant peak shape is theoretically considered. Extracolumn distortion factors have been characterized on experimental peaks.
Characterization of extracolumn and concentration-dependent distortion of chromatographic peaks by Edgeworth-Cramer series
DONDI, Francesco;REMELLI, Maurizio
1984
Abstract
The Edgeworth-Cramér series peak handling method has been used to detect the onset of small variations of chromatographic peak shape when the mass of solute injected is increased. The eflect of extracolumn distortion on statistical peak parameters and on the resultant peak shape is theoretically considered. Extracolumn distortion factors have been characterized on experimental peaks.File in questo prodotto:
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