Photolysis of tetracyanoethylene in the presence of (η-C5H5)2M (M = Ru, Os) gives the novel (η-C5H5)2M · TCNE complexes. Charge transfer absorptions are identified for these compounds. Selective irradiation of the complexes gives metallocenium cations and TCNE⨪ anion radicals as the primary photoproducts.
Photochemical synthesis and reaction of d6 metallocenes—tetracyanoethylene charge-transfer complexes
DUATTI, AdrianoSecondo
;
1978
Abstract
Photolysis of tetracyanoethylene in the presence of (η-C5H5)2M (M = Ru, Os) gives the novel (η-C5H5)2M · TCNE complexes. Charge transfer absorptions are identified for these compounds. Selective irradiation of the complexes gives metallocenium cations and TCNE⨪ anion radicals as the primary photoproducts.File in questo prodotto:
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