An unusual, facile cleavage of C-N bonds of diethylenetriamine (H 2NCH2CH2NHCH2CH2NH 2 = dien) promoted by the reaction with the rhenium(V) nitrido complex [ReNCl2(PPh3)2] to yield β-alanine (H2NCH2CH2CO2H = β-ala) is reported.
Metal promoted cleavage of diethylenetriamine to give β-alanine
DUATTI, Adriano
1992
Abstract
An unusual, facile cleavage of C-N bonds of diethylenetriamine (H 2NCH2CH2NHCH2CH2NH 2 = dien) promoted by the reaction with the rhenium(V) nitrido complex [ReNCl2(PPh3)2] to yield β-alanine (H2NCH2CH2CO2H = β-ala) is reported.File in questo prodotto:
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