C14H17NO4 crystallizes in the monoclinic space groupP21/n (Z=4) witha=10.208(2),b=10.888(2),c=11.909(2) Å, andβ=90.89(2)°. The structure was solved by direct methods and refined by full-matrix LSQ to anR factor of 0.036. The 4-oxo-1,3-dioxane ring is in a slightly distorted O(1)-sofa conformation flattened at the C(4) end with the 5-isopropyl substituent in a pseudoaxial position and planar lactone group. The molecules form dimers by means of intermolecular N-H⋯O(4) hydrogen bonds of 3.091(2) Å. The1H NMR spectrum of the title compound shows unusual features.

Crystal structure of 5-benzoylamino-5-isopropyl-4-oxo-1,3-dioxane

GILLI, Gastone
Penultimo
;
BERTOLASI, Valerio
Ultimo
1986

Abstract

C14H17NO4 crystallizes in the monoclinic space groupP21/n (Z=4) witha=10.208(2),b=10.888(2),c=11.909(2) Å, andβ=90.89(2)°. The structure was solved by direct methods and refined by full-matrix LSQ to anR factor of 0.036. The 4-oxo-1,3-dioxane ring is in a slightly distorted O(1)-sofa conformation flattened at the C(4) end with the 5-isopropyl substituent in a pseudoaxial position and planar lactone group. The molecules form dimers by means of intermolecular N-H⋯O(4) hydrogen bonds of 3.091(2) Å. The1H NMR spectrum of the title compound shows unusual features.
1986
Glowka, Ml; Kaminski, Zj; Gilli, Gastone; Bertolasi, Valerio
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/460672
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