Four new silver(I) naphthalenedisulphonate complexes, [Ag 2 (1,5-nds) (β-Pic) 4 ]·2H 2 O (1), [Ag 2 (1,5-nds)(γ-Pic) 4 ]·6H 2 O (2), [Ag 2 (2,6-nds) (β-Pic) 4 ] (3) and [Ag 2 (2,6-nds) (γ-Pic) 4 ]·2H 2 O (4) have been synthesized using appropriate starting materials at ambient temperature and normal reaction conditions and fully characterized by spectroscopic methods (FT-IR, NMR). The structures of all the four complexes were determined using single crystal X-ray diffraction techniques and a detailed analysis of the role of weak non-covalent interactions in the solid state (hydrogen bonds, argentophylic interactions, π⋯π interactions) were investigated. Antibacterial activities of all complexes have been evaluated, indicating their high efficacy against both gram positive and gram negative bacterial strains.

Synthesis and characterization of new silver(I) naphthalenedisulfonate complexes with heterocyclic N-donor ligands: Packing analyses and antibacterial studies

Ferretti, Valeria
Ultimo
2019

Abstract

Four new silver(I) naphthalenedisulphonate complexes, [Ag 2 (1,5-nds) (β-Pic) 4 ]·2H 2 O (1), [Ag 2 (1,5-nds)(γ-Pic) 4 ]·6H 2 O (2), [Ag 2 (2,6-nds) (β-Pic) 4 ] (3) and [Ag 2 (2,6-nds) (γ-Pic) 4 ]·2H 2 O (4) have been synthesized using appropriate starting materials at ambient temperature and normal reaction conditions and fully characterized by spectroscopic methods (FT-IR, NMR). The structures of all the four complexes were determined using single crystal X-ray diffraction techniques and a detailed analysis of the role of weak non-covalent interactions in the solid state (hydrogen bonds, argentophylic interactions, π⋯π interactions) were investigated. Antibacterial activities of all complexes have been evaluated, indicating their high efficacy against both gram positive and gram negative bacterial strains.
2019
Kumar, Santosh; Sharma, Raj Pal; Venugopalan, Paloth; Gondil, Vijay Singh; Chhibber, Sanjay; Ferretti, Valeria
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2401484
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