Reaction of Cu(NO3)2·3H2O and 2-hydroxy-3-methoxybenzaldehyde (HL) in methanolic medium results [CuL2]·4H2O (1) [L- = 3-methoxy-2-oxo-benzaldehyde]. The complex was characterized by elemental analysis, IR, single crystal X-ray structure determination and DFT calculation. The X-ray single crystal structure determination reveals that 1 is a discrete mononuclear four coordinated complex with the metal in square planar coordination geometry and four lattice water molecules. The complex form dimer around the center of symmetry with short Cu.

Bis-chelated-(3-methoxy-2-oxo-benzaldehyde)–copper(II) complex: Synthesis, crystal structure, fluorescence property, DFT calculation, and catecholase activity

BERTOLASI, Valerio;
2015

Abstract

Reaction of Cu(NO3)2·3H2O and 2-hydroxy-3-methoxybenzaldehyde (HL) in methanolic medium results [CuL2]·4H2O (1) [L- = 3-methoxy-2-oxo-benzaldehyde]. The complex was characterized by elemental analysis, IR, single crystal X-ray structure determination and DFT calculation. The X-ray single crystal structure determination reveals that 1 is a discrete mononuclear four coordinated complex with the metal in square planar coordination geometry and four lattice water molecules. The complex form dimer around the center of symmetry with short Cu.
2015
Mistri, Soumen; Bertolasi, Valerio; Manna, Subal Chandra
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2336674
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