The interaction of hydrogen sulfide and hydrogen persulfide with protons and lithium cations was examined by means of ab initio 6–31G* calculations. The influence of the correlation energy for selected complexes was estimated. Contrary to former results, it can be indicated that second-row hydrides show a consistent interaction behaviour to metal cations and protons. Similarities and differences with the corresponding first-row complexes are discussed.
Proton and Lithium cation interactions with hydrogen sulfide and hydrogen persulfide
CIMIRAGLIA, Renzo;
1989
Abstract
The interaction of hydrogen sulfide and hydrogen persulfide with protons and lithium cations was examined by means of ab initio 6–31G* calculations. The influence of the correlation energy for selected complexes was estimated. Contrary to former results, it can be indicated that second-row hydrides show a consistent interaction behaviour to metal cations and protons. Similarities and differences with the corresponding first-row complexes are discussed.File in questo prodotto:
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