A new photocatalyst (Na4W10O32/SiO2/BTESE) has been prepared by simultaneous hydrolysis of tetraethyl orthosilicate (TEOS) and 1,2-bis(triethoxysilyl)ethane (BTESE) in the presence of Na4W10O32. This material is able to scavenge and accumulate significant amounts of toluene from water solutions saturated with the hydrocarbon. This is due to its large specific surface area, micro and mesoporosity, and, above all, to the high hydrophobicity of its surface. Moreover, photoexcited Na4W10O32/SiO2/BTESE show savery strong oxidizing ability, allowing an almost complete mineralization of toluene to CO2 through the formation and reactivity of OH• radicals. Considering both the sorption capability and the photocatalytic activity, the efficiency of Na4W10O32/SiO2/BTESE is significantly higher than those of Na4W10O32/SiO2 and Na4W10O32dissolved in homogeneous solution. At the end of a cycle of reaction, Na4W10O32/SiO2/BTESE is reusable without any loss of activity opening to the development of new efficient and stable photocatalytic systems addressed to clean wastewater containing aromatic hydrocarbons.
Hydrophobic W10O324-/silica photocatalyst for toluene oxidation in water system
MOLINARI, Alessandra;MALDOTTI, Andrea
2013
Abstract
A new photocatalyst (Na4W10O32/SiO2/BTESE) has been prepared by simultaneous hydrolysis of tetraethyl orthosilicate (TEOS) and 1,2-bis(triethoxysilyl)ethane (BTESE) in the presence of Na4W10O32. This material is able to scavenge and accumulate significant amounts of toluene from water solutions saturated with the hydrocarbon. This is due to its large specific surface area, micro and mesoporosity, and, above all, to the high hydrophobicity of its surface. Moreover, photoexcited Na4W10O32/SiO2/BTESE show savery strong oxidizing ability, allowing an almost complete mineralization of toluene to CO2 through the formation and reactivity of OH• radicals. Considering both the sorption capability and the photocatalytic activity, the efficiency of Na4W10O32/SiO2/BTESE is significantly higher than those of Na4W10O32/SiO2 and Na4W10O32dissolved in homogeneous solution. At the end of a cycle of reaction, Na4W10O32/SiO2/BTESE is reusable without any loss of activity opening to the development of new efficient and stable photocatalytic systems addressed to clean wastewater containing aromatic hydrocarbons.I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
