Several cyanide-bridged polynuclear complexes have been synthesized in the context of intramolecular energy and electron transfer studies. A valencelocalized description is generally appropriate for such complexes. Within such a localized picture, however, the cyanide bridge is found to provide a remarkable degree of metal-metal electronic coupling. This conclusion can be drawn from a variety of experimental results. Specific attention is devoted here to the spectroscopic observation of appreciable second-order interactions between remote (i.e., non directly bridged) sites in a polynuclear complex. © 1993.

Electronic coupling between remote metal centers in cyanobridged polynuclear complexes

SCANDOLA, Franco;ARGAZZI, Roberto;BIGNOZZI, Carlo Alberto;CHIORBOLI, Claudio;INDELLI, Maria Teresa;RAMPI, Maria Anita
1993

Abstract

Several cyanide-bridged polynuclear complexes have been synthesized in the context of intramolecular energy and electron transfer studies. A valencelocalized description is generally appropriate for such complexes. Within such a localized picture, however, the cyanide bridge is found to provide a remarkable degree of metal-metal electronic coupling. This conclusion can be drawn from a variety of experimental results. Specific attention is devoted here to the spectroscopic observation of appreciable second-order interactions between remote (i.e., non directly bridged) sites in a polynuclear complex. © 1993.
1993
Scandola, Franco; Argazzi, Roberto; Bignozzi, Carlo Alberto; Chiorboli, Claudio; Indelli, Maria Teresa; Rampi, Maria Anita
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/1683849
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