Peroxomolybdenum(VI) complexes bearing monodentate chiral ligands were found to exhibit asymmetric induction in the epoxidation of trans-2-octene. Under identical experimental conditions, bidentate-containihg complexes gave similar results. The implications of these findings on the elucidation of the mechanism of oxygen transfer from the peroxomolybdenum complexes to the substrate are discussed. © 1986.
Asymmetric Epoxidation by Mo(VI)-Peroxocomplexes: A Mechanistic Analysis
BORTOLINI, Olga;
1986
Abstract
Peroxomolybdenum(VI) complexes bearing monodentate chiral ligands were found to exhibit asymmetric induction in the epoxidation of trans-2-octene. Under identical experimental conditions, bidentate-containihg complexes gave similar results. The implications of these findings on the elucidation of the mechanism of oxygen transfer from the peroxomolybdenum complexes to the substrate are discussed. © 1986.File in questo prodotto:
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