The gas‐phase unimolecular decomposition of [M‐H]− of 1,3‐dithiolane S‐oxides has been studied using Fast Atom Bombardment (FAB) for anion generation. A comparison with the reactivity in solution is made and some differences or similarities with the chemistry in the gas‐phase are discussed. The decomposition pathways of the molecules under investigation are function of the substituents. Copyright © 1990 Journal of Heterocyclic Chemistry
FAB‐Induced deprotonation, elimination and decomposition of 1,3‐dithiolane S‐oxides
BORTOLINI, Olga;
1990
Abstract
The gas‐phase unimolecular decomposition of [M‐H]− of 1,3‐dithiolane S‐oxides has been studied using Fast Atom Bombardment (FAB) for anion generation. A comparison with the reactivity in solution is made and some differences or similarities with the chemistry in the gas‐phase are discussed. The decomposition pathways of the molecules under investigation are function of the substituents. Copyright © 1990 Journal of Heterocyclic ChemistryFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
