Aerobic oxidation of PriOH to acetone with parallel reduction of dioxygen to hydrogen peroxide is observed for acid PriOH–H2O solutions of peroxovanadates. Spectroscopic evidence, obtained with a combined use of 51V-NMR, UV–VIS and ESI-MS techniques, is presented for a monoperoxovanadium-catalysed inner-sphere oxidation of the alcohol coordinated to the metal center.
Aerobic oxidation of isopropanol catalysed by peroxovanadium complexes: mechanistic insights
BORTOLINI, Olga;
2001
Abstract
Aerobic oxidation of PriOH to acetone with parallel reduction of dioxygen to hydrogen peroxide is observed for acid PriOH–H2O solutions of peroxovanadates. Spectroscopic evidence, obtained with a combined use of 51V-NMR, UV–VIS and ESI-MS techniques, is presented for a monoperoxovanadium-catalysed inner-sphere oxidation of the alcohol coordinated to the metal center.File in questo prodotto:
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