Electrospray Ionization Mass Spectrometry (ESI-MS) obtained clearly indicate that the exchange reactions measurements and ab initio calculations on [OV(O2)(H2O)m- between water and methanol molecules, within the (CH3OH)n]+ (m,n: 0–4) peroxo cations have been carried out. coordination sphere of monoperoxo-vanadium complexes, is This experimental technique allowed the direct observation a conceivable and fast process. of the above mentioned species for the first time. The results
Direct Evidence of Solvent-Peroxovanadium Clusters by Electrospray Ionization Mass Spectrometry
BORTOLINI, Olga;
1998
Abstract
Electrospray Ionization Mass Spectrometry (ESI-MS) obtained clearly indicate that the exchange reactions measurements and ab initio calculations on [OV(O2)(H2O)m- between water and methanol molecules, within the (CH3OH)n]+ (m,n: 0–4) peroxo cations have been carried out. coordination sphere of monoperoxo-vanadium complexes, is This experimental technique allowed the direct observation a conceivable and fast process. of the above mentioned species for the first time. The resultsFile in questo prodotto:
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