The synthesis of (R)- and (S)-3-(4-hydroxyphenyl)-1-methylpropyl-β-D-glucopyranosides has been achieved by two enzymatic steps, namely an oxido-reduction step involving alcohol dehydrogenases from different origin for the preparation of both aglycones in enantiomeric pure form, and a transglycosidation step involving a thermophilic β-glucosidase from the archaeon Sulfolobus solfataricus. © 1996 OPA (Overseas Publishers Association) Amsterdam B.V. Published in The Netherlands under license by Gordon and Breach Science Publishers SA.
Enzymatic routes for the synthesis of rhododendrin and epi-rhododendrin
FANTIN, Giancarlo;FOGAGNOLO, Marco
1996
Abstract
The synthesis of (R)- and (S)-3-(4-hydroxyphenyl)-1-methylpropyl-β-D-glucopyranosides has been achieved by two enzymatic steps, namely an oxido-reduction step involving alcohol dehydrogenases from different origin for the preparation of both aglycones in enantiomeric pure form, and a transglycosidation step involving a thermophilic β-glucosidase from the archaeon Sulfolobus solfataricus. © 1996 OPA (Overseas Publishers Association) Amsterdam B.V. Published in The Netherlands under license by Gordon and Breach Science Publishers SA.File in questo prodotto:
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