Reactions of dppf with labile technetium and rhenium precursors such as [M(N)Cl4]- and [M(NPh)Cl3(PPh3)2] yield the monomeric mono-substituted [M(N)Cl2(dppf)] and [M(NPh)Cl3(dppf)] complexes, where the diphosphinoferrocenyl fragment coordinates on the equatorial plane of a distorted square pyramid or of a distorted octahedron, respectively. © 2001 Elsevier Science B.V.
Technetium and rhenium heterocomplexes containing the diphenylphosphinoferrocenyl fragment
DUATTI, Adriano;BOSCHI, Alessandra;UCCELLI, Licia;
2001
Abstract
Reactions of dppf with labile technetium and rhenium precursors such as [M(N)Cl4]- and [M(NPh)Cl3(PPh3)2] yield the monomeric mono-substituted [M(N)Cl2(dppf)] and [M(NPh)Cl3(dppf)] complexes, where the diphosphinoferrocenyl fragment coordinates on the equatorial plane of a distorted square pyramid or of a distorted octahedron, respectively. © 2001 Elsevier Science B.V.File in questo prodotto:
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