A new asymmetric two-dimensional synthesis of 1,4-diamino 2,3-diols is illustrated by double addition of benzylmagnesium chloride to the bis- nitrone derived from (R,R)-tartraldehyde and reduction of the resulting dihydroxylamines.
Synthesis of C-2-symmetric dibenzyldiamino diols by double stereoselective Grignard addition to (S,S)-tartraldehyde dinitrone
DONDONI, Alessandro;PERRONE, Daniela;
1998
Abstract
A new asymmetric two-dimensional synthesis of 1,4-diamino 2,3-diols is illustrated by double addition of benzylmagnesium chloride to the bis- nitrone derived from (R,R)-tartraldehyde and reduction of the resulting dihydroxylamines.File in questo prodotto:
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