The conformation of side chain –SCH2COOCH3 in title compounds in crystal agrees with the reactivity of these compounds in base catalysed ring closure in solution. In the 2,4-dinitro derivative, the side chain is oriented towards the unsubstituted ortho-position of benzene ring, in the case of the 2-methoxycarbonyl derivative towards this substituent.

Structure and base catalysed cyclization of methyl (2,6-disubstituted-4-nitrophenylsulphanyl)ethanoates

BERTOLASI, Valerio;
2003

Abstract

The conformation of side chain –SCH2COOCH3 in title compounds in crystal agrees with the reactivity of these compounds in base catalysed ring closure in solution. In the 2,4-dinitro derivative, the side chain is oriented towards the unsubstituted ortho-position of benzene ring, in the case of the 2-methoxycarbonyl derivative towards this substituent.
2003
Bertolasi, Valerio; Dudova, K; Simunek, P; Cerny, J; Machacek, V.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/1198132
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